Section 1: Product and Company Identification
Jacobs Stone Products Product Name: ConSANDtrate / Kwixsand
1210 Pierce Street Generic Name:
San Saba, Texas 76877 Synonyms: NA
Business: 325-372-3298 Product Description: Cement/sand mixture for mortar
FAX: 325-372-5969 CAS # NA - mixture
Date of Revision: 25 November 2009
Section 2: Hazard Identification
HMIS HEALTH 1
HMIS FLAMMABILITY 0
HMIS REACTIVITY 0
PERSONAL PROTECTION E
Dense powder, color varies. Emergency Overview: May irritate eyes and skin. May be harmful if ingested or inhaled. Use with adequate ventilation. A2 - suspected human carcinogen.
OSHA Regulatory Status: This material is considered hazardous under the OSHA standard.
WHMIS Classification: D2A, E
Potential Health Effects:
Inhalation: May cause irritation to the moist mucous membranes of the nose, throat, and upper respiratory system. Prolonged exposure may cause delay lung damage including silicosis. Silica in sand is a suspected and known carcinogen by inhalation.
Ingestion: Ingestion of small amounts is not expected to produce serious effects. Ill effects and gastric disturbances are expected from ingesting large amounts.
Skin Contact: May cause irritation. Wet material can cause greater irritation and caustic burns from prolonged contact.
Eye Contact: Can causes irritation, redness and tearing. Exposure to wet material can cause caustic burns and blindness. May scratch cornea if rubbed.
Chronic Exposure: No information found.
Aggravation of Pre-existing Conditions: No information found.
Target Organs: Eyes, skin
Section 3: Composition / Information On Ingredients
Component Common Names, Synonyms CAS # EINECS Weight %
Sand Silica, quartz, silicon dioxide 14808-60-7 238-878-4 > 90
Portland cement Calcium silicate mixture 65997-15-1 266-043-4 < 5
Non-hazardous components may or may not be listed. Carcinogens are listed when present at 0.1% or more; components which are otherwise hazardous according to OSHA are listed when present at 1.0% or more. This is not intended to be complete compositional disclosure. See Section 15 for applicable states right to know and other regulatory information.
Section 4: First Aid Measures
Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention immediately.
Ingestion: DO NOT induce vomiting. Never give anything by mouth to an unconscious person. Get medical attention immediately.
Skin: Immediately flush skin with plenty of water for at least 15 minutes. Get medical attention if irritation develops.
Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately.
Note to Physicians: N/A
Section 5: Fire Fighting Measures
Fire: Flash point: Does not burn
Explosion: Not considered an explosion hazard. The dust from this product is not expected to be an explosion hazard.
Extinguishing Media: Water spray, dry chemical, alcohol foam or carbon dioxide. Water spray may be used to keep fire exposed containers cool.
Special Precautions: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full facepiece operated in the pressure demand or other positive pressure mode.
NFPA Rating: Health - 1 Flammability - 1 Reactivity - 0 Other - NA
Section 6: Accidental Release Measures
Ventilate area of leak or spill. Remove all sources of ignition. Wear appropriate personal protective equipment as specified in Section 8. Isolate hazard area. Keep unnecessary and unprotected personnel from entering. Contain and recover solid when possible and place in a chemical waste container. Do not flush to sewer! US Regulations (CERCLA) require reporting spills and releases to soil, water and air in excess of reportable quantities. The toll free number for the US Coast Guard National Response Center is (800) 424-8802.
Section 7: Handling and Storage
Keep in a tightly closed container, stored in a cool, dry, ventilated area. Protect against physical damage. Isolate from any source of heat or ignition. Separate from incompatibles, combustibles, organic or other readily oxidizable materials. Containers of this material may be hazardous when empty since they retain product residues (liquid, vapors); observe all warnings and precautions listed for the product.
Section 8: Exposure Control / Personal Protection
Exposure Guidelines:
Component CAS # OSHA PEL ACGIH TLV NIOSH TLV
Sand 14808-60-7 None established 0.025 mg/m3 Respirable Quartz 0.05 mg/m3 TWA
50 mg/m3 IDLH
Portland cement 65997-15-1 5 mg respirable dust/m3 10 mg respirable dust/m3 5 mg/m3 TWA
5000 mg/m3 IDLH
Personal Protective Equipment:
Skin Contact: Wear impervious protective clothing, including boots, gloves or coveralls, as appropriate, to prevent skin contact.
Eye Contact: Use chemical safety goggles and/or full face shield to avoid contact with eyes. Maintain eye wash fountain and quick-drench facilities in work area.
Inhalation: Use NIOSH-approved dust respirator if exposure is unknown or exceeds permissible limits. A respiratory protection program that meets OSHA's 29 CFR 1910.134 or ANSI Z88.2 requirements must be followed whenever workplace conditions warrant respirator use. WARNING: Air-purifying respirators do not protect workers in oxygen-deficient atmospheres.
Engineering Controls: A system of local and/or general exhaust is recommended to keep employee exposures below the Airborne Exposure Limits. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH document, Industrial Ventilation, A Manual of Recommended Practices, most recent edition, for details.
Section 9: Physical and Chemical Properties
Appearance Dense powder, color varies Specific Gravity (g/mL) 1.8 - 2.5
Odor Negligible pH N/A
Odor Threshold ND Solubility in water Very low
Melting Point ND % Volatiles None
Boiling Point ND Evaporation Rate ND
Flash Point NA Vapor Pressure ND
Section 10: Stability and Reactivity
Chemical Stability: This product is stable in closed containers at room temperature. Exposure to water or moisture will cause reaction with hardening and generation of heat.
Hazardous Decomposition Products: Calcium hydroxide will result from mixing with water.
Hazardous Polymerization: Will not occur.
Incompatibilities: Water, acids
Conditions to Avoid: Wet conditions, high humidity.
Section 11: Toxicological Information
Acute Dose Effects: Eyes: No information found.
Skin: No information found.
Oral: No information found.
Inhalation: No information found.
Section 12: Ecological Information
Environmental Fate: This product is not expected to bioaccumulate. This product is not readily biodegradable.
Ecotoxicity: No information found.
Section 13: Disposal Considerations
As a waste, this material IS NOT considered a HAZARDOUS WASTE under RCRA (29 CFR 261).
Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state and local requirements.
Section 14: Transport Information
U.S. Domestic Ground Proper Shipping Name: Not regulated for transport
DOT Hazard Class: N/A
UN Number: N/A
Packing Group: N/A
U.S. Domestic Air Proper Shipping Name: Not regulated for transport
DOT Hazard Class: N/A
UN Number: N/A
Packing Group: N/A
Canadian TDG Proper Shipping Name: Not regulated for transport
DOT Hazard Class: N/A
UN Number: N/A
Packing Group: N/A
International Air Proper Shipping Name: Not regulated for transport
DOT Hazard Class: N/A
UN Number: N/A
Packing Group: N/A
CERCLA Reportable Quantity (RQ): N/A
Releases exceeding the reportable quantity (RQ) must be reported to the National Response Center (800) 424-8802.
This data provided for information only. The description shown may not apply to all shipping situations. Consult 49 CFR, or appropriate regulations to properly classify your shipment for transportation.
Section 15: Regulatory Information
TSCA Chemical Inventory: All of the chemicals in this product are listed on the TSCA Inventory.
TSCA Sec 4 Chemical Test Rule: None of the chemicals in this product are under a Chemical Test Rule.
TSCA Sec 8(d): None of the chemicals in this product are on the Health and Safety Reporting List.
TSCA Sec 12(b) Notices of Export: None of the chemicals in this product are on this list.
TSCA Significant New Use Rule (SNUR): None of the chemicals in this product are on this list.
SARA Sec 302 (EHS) TPQ: None of the chemicals in this product have a TPQ.
SARA Sec 302 (EHS) RQ: None of the chemicals in this product have a RQ.
SARA Sec 311/312: Acute - YES; Chronic - YES; Fire - NO; Release of Pressure - NO; Reactivity - NO
SARA 313 List: None of the chemicals in this product is reportable under Section 313 Title III and 40 CFR Part 372.
CERCLA Hazardous Substances and corresponding RQs: N/A.
RCRA: None of the chemicals in this product are on this list.
Clean Air Act: Hazardous Air Pollutants? NO Class 1 Ozone Depletors? NO Class 2 Ozone Depletors? NO
Clean Water Act: Hazardous Substance? NO Priority Pollutant? NO Toxic Pollutant? NO
Chemical Weapons Convention: None of the chemicals in this product are on this list.
Drug Enforcement Agency (DEA) CDTA: None of the chemicals in this product are on this list.
OSHA: None of the chemicals in this product are considered Highly Hazardous by OSHA.
State Right-to-Know Lists: Sand is found on the Right-to-Know lists of New Jersey, Pennsylvania, Massachusetts and Minnesota.
California Proposition 65: This product contains sand, a chemical known to the State of California to cause cancer.
Canadian: This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all of the information required by the Controlled Products Regulations.
The components in this product are listed, or exempt from listing, on the Canadian Domestic Substances List.
WHMIS Classification: D2A, E
Ingredient Disclosure List: None of the chemicals in this product are on this list.
Section 16: Other Information
Abbreviations and acronyms used:
ACGIH American Conference of Governmental Industrial Hygienists NA not applicable, not available
ANSI American National Standards Institute NIOSH National Institute for Occupational Safety and Health
atm atmosphere (pressure unit) ND not determined
BOD biological oxygen demand NFPA National Fire Prevention Association
CAS Chemical Abstracts Service NTP National Toxicology Program
CC closed cup OC open cup
CDTA Chemical Drug and Trafficking Act OSHA Occupational Safety and Health Administration
COC Cleveland Open Cup Part partition
COD chemical oxygen demand PEL permissible exposure limits
coeff. coefficient ppb parts per billion
CFR Code of Federal Regulations PPE personal protective equipment
CPR cardio-pulmonary resuscitation ppm parts per million
DEA Drug Enforcement Agency psi pounds per square inch
DOT Department of Transportation RCRA Resource Conservation and Recovery Act
FDA Food and Drug Administration RQ Reportable quantity
IARC Internat'l Agency for Research on Cancer RTK Right to Know
IDLH immediate danger to life and health SARA Superfund Amendments and Reauthorization Act
kg kilogram STEL short-term exposure limit
L liter TCC Tagliabue Closed Cup
LC50 median lethal concentration TPQ threshold planning quantity
LD50 median lethal dose TQ threshold quantity
LEL lower explosive limit TSCA Toxic Substances Control Act
mg milligram TWA time-weighted average
mL milliliter UEL upper explosive limit
This document was prepared in accordance with 29 CFR 1910.1200 and ANSI Z400.1-2005.
Prepared by Douglas R. Chrisope on 25 November 2009.
DISCLAIMER: Although the information and recommendations set forth herein (hereinafter "Information") are presented in good faith and believed to be correct as of the date hereof, the Company makes no representations as to the completeness or accuracy thereof. Information is supplied upon the condition that the persons receiving this MSDS will make their own determination as to its suitability for their intended purposes prior to use. Since the product is within the exclusive control of the user, it is the user's obligation to determine the conditions of safe use of this product. Such conditions should comply with all Federal Regulations concerning the Product. It must be recognized that the physical and chemical properties of any product may not be fully understood and that new, possibly hazardous products may arise from reactions between chemicals. The information given in this data sheet is based on our present knowledge and shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. NO REPRESENTATIONS OR WARRANTIES, EITHER EXPRESS OR IMPLIED, OF MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE OR OF ANY OTHER NATURE ARE MADE HEREUNDER WITH RESPECT TO INFORMATION OR THE PRODUCT TO WHICH INFORMATION REFERS.
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